39.8CHEM-PHMay 13
Physics-Guided Concentration Inference from Resistance Transients in a Mixed-Phase SnO-SnO$_2$ Carbon Monoxide Sensor with p-n SwitchingSani Biswas, Preetam Singh, Amit Kumar Gangwar
This work presents a physics-guided machine-learning framework for carbon monoxide concentration inference from experimentally measured resistance transients of a mixed-phase SnO-SnO$_2$ material gas sensor exhibiting temperature-dependent p-n switching behavior. Cycle-level transient responses are represented through physically interpretable descriptors and complemented by compact fast Fourier transform (FFT) and discrete wavelet transform (DWT)-based summaries. Using leakage-aware grouped cross-validation, we study both multi-class concentration classification and continuous concentration regression for the p-type and n-type sensing regimes separately. Across both regimes, fused features provide the strongest overall performance, while the physics-guided descriptor block remains highly competitive, indicating that the dominant concentration information is already encoded in physically meaningful transient dynamics. The p-type branch shows the best concentration-class discrimination, with the fused Random Forest classifier reaching approximately $96.5\%$ accuracy, whereas the n-type branch yields the best quantitative concentration estimation, with the fused Random Forest regressor achieving an MAE$\approx 1.48$ ppm and an R$^2$ $\approx 0.992$. These results reveal a clear dual-regime behavior: p-type sensing is particularly favorable for classification, whereas n-type sensing is more favorable for high-fidelity regression. More broadly, the study demonstrates that leakage-aware, cycle-level, physics-guided machine learning can extend conventional gas-sensing analysis beyond single-response metrics while preserving physical interpretability
14.2LGMay 4
Physics-Informed Neural Learning for State Reconstruction and Parameter Identification in Coupled Greenhouse Climate DynamicsSani Biswas, Khursheed J. Ansari, Md. Nasim Akhtar
Physics-informed neural networks (PINNs) have recently emerged as a promising framework for integrating data-driven learning with physical knowledge. In this work, we propose a coupled PINN approach for the joint reconstruction of indoor temperature and humidity dynamics in greenhouse environments, together with simultaneous identification of key model parameters. The method incorporates a reduced-order physically motivated model into the learning process, enabling consistent estimation under sparse and noisy observations. The artificial intelligence contribution lies in the development of a coupled physics-informed neural learning framework that integrates governing dynamical constraints into neural network training, while the engineering application focuses on greenhouse climate state reconstruction and parameter identification. The proposed framework is evaluated on a controlled synthetic benchmark that mimics diurnal forcing conditions. Compared with a purely data-driven neural network baseline, the coupled PINN achieves improved reconstruction accuracy, reducing temperature and humidity errors while maintaining high coefficients of determination. The improvement is particularly pronounced in the humidity channel, where latent moisture dynamics are more difficult to infer from limited measurements. In addition to accurate state reconstruction, the method successfully recovers the dominant physical parameters governing the system dynamics, demonstrating its ability to learn interpretable representations beyond data interpolation. These results highlight the potential of physics-informed learning for greenhouse climate modeling and, more broadly, for data-scarce environmental systems.