Andreas Münch

Alpha Albert Lee, Andreas Münch, Endre Süli

In this work, the sharp interface limit of the degenerate Cahn-Hilliard equation (in two space dimensions) with a polynomial double well free energy and a quadratic mobility is derived via a matched asymptotic analysis involving exponentially large and small terms and multiple inner layers. In contrast to some results found in the literature, our analysis reveals that the interface motion is driven by a combination of surface diffusion flux proportional to the surface Laplacian of the interface curvature and an additional contribution from nonlinear, porous-medium type bulk diffusion, For higher degenerate mobilities, bulk diffusion is subdominant. The sharp interface models are corroborated by comparing relaxation rates of perturbations to a radially symmetric stationary state with those obtained by the phase field model.

Alpha A Lee, Andreas Münch, Endre Süli

Phase field models frequently provide insight to phase transitions, and are robust numerical tools to solve free boundary problems corresponding to the motion of interfaces. A body of prior literature suggests that interface motion via surface diffusion is the long-time, sharp interface limit of microscopic phase field models such as the Cahn-Hilliard equation with a degenerate mobility function. Contrary to this conventional wisdom, we show that the long-time behaviour of degenerate Cahn-Hilliard equation with a polynomial free energy undergoes coarsening, reflecting the presence of bulk diffusion, rather than pure surface diffusion. This reveals an important limitation of phase field models that are frequently used to model surface diffusion.