CHEM-PHCELGJun 8, 2021

Non-Autoregressive Electron Redistribution Modeling for Reaction Prediction

arXiv:2106.07801v126 citations
Originality Highly original
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This addresses the challenge of efficient and interpretable reaction prediction in synthetic chemistry, offering a novel paradigm that improves speed and accuracy over existing methods.

The paper tackles the problem of predicting chemical reaction products by introducing a non-autoregressive method that models reactions as electron redistribution, achieving a new state-of-the-art top-1 accuracy on the USPTO-MIT dataset and at least 27 times faster inference speed.

Reliably predicting the products of chemical reactions presents a fundamental challenge in synthetic chemistry. Existing machine learning approaches typically produce a reaction product by sequentially forming its subparts or intermediate molecules. Such autoregressive methods, however, not only require a pre-defined order for the incremental construction but preclude the use of parallel decoding for efficient computation. To address these issues, we devise a non-autoregressive learning paradigm that predicts reaction in one shot. Leveraging the fact that chemical reactions can be described as a redistribution of electrons in molecules, we formulate a reaction as an arbitrary electron flow and predict it with a novel multi-pointer decoding network. Experiments on the USPTO-MIT dataset show that our approach has established a new state-of-the-art top-1 accuracy and achieves at least 27 times inference speedup over the state-of-the-art methods. Also, our predictions are easier for chemists to interpret owing to predicting the electron flows.

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