CHEM-PHLGFeb 5, 2024

Gaussian Plane-Wave Neural Operator for Electron Density Estimation

arXiv:2402.04278v29 citationsh-index: 6ICML
Originality Highly original
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This work addresses a fundamental problem in chemistry and materials science for density functional theory simulations, with incremental improvements through a hybrid method.

The paper tackled electron density prediction for chemical systems by introducing the Gaussian plane-wave neural operator (GPWNO), which uses plane-wave and Gaussian-type orbital bases to represent high- and low-frequency components, achieving superior performance over ten baselines on QM9, MD, and material project datasets.

This work studies machine learning for electron density prediction, which is fundamental for understanding chemical systems and density functional theory (DFT) simulations. To this end, we introduce the Gaussian plane-wave neural operator (GPWNO), which operates in the infinite-dimensional functional space using the plane-wave and Gaussian-type orbital bases, widely recognized in the context of DFT. In particular, both high- and low-frequency components of the density can be effectively represented due to the complementary nature of the two bases. Extensive experiments on QM9, MD, and material project datasets demonstrate GPWNO's superior performance over ten baselines.

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